Roming Formaldehyde, a litterature review
نویسنده
چکیده
A collection of articles related to roaming, mostly in formaldehyde, H2CO. Quoted sections are set in italics. There are four prinary groups that have published theories tackling roaming. Harding and Klippenstein take a rather standard transition state theory perspective, but subdivide configuration using “centrifugal” and “entropic” barriers rather than energetic ones alone [23]. Jordan and Kable construct a two-parameter theory based partitioning the results of a variational transition state theory with a phase-space volume summation [29]. Wiggins and Ezra take a dynamical systems perspective and seek phase-space structures giving rise to roaming [34]. Tsai and Lin interpret the output of an impulsive model for photo-fragmentation [38].
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